ASTM E354 : 14

Standard Test Methods for Chemical Analysis of High-Temperature, Electrical, Magnetic, and Other Similar Iron, Nickel, and Cobalt Alloys

Standard Details

1.1 These test methods cover the chemical analysis of high-temperature, electrical, magnetic, and other similar iron, nickel, and cobalt alloys having chemical compositions within the following limits:

Element	Composition Range, %

Aluminum	0.005	to	18.00
Beryllium	0.001	to	0.05
Boron	0.001	to	1.00
Calcium	0.002	to	0.05
Carbon	0.001	to	1.10
Chromium	0.10	to	33.00
Cobalt	0.10	to	75.00
Columbium (Niobium)	0.01	to	6.0
Copper	0.01	to	10.00
Iron	0.01	to	85.00
Magnesium	0.001	to	0.05
Manganese	0.01	to	3.0
Molybdenum	0.01	to	30.0
Nickel	0.10	to	84.0
Nitrogen	0.001	to	0.20
Phosphorus	0.002	to	0.08
Silicon	0.01	to	5.00
Sulfur	0.002	to	0.10
Tantalum	0.005	to	10.0
Titanium	0.01	to	5.00
Tungsten	0.01	to	18.00
Vanadium	0.01	to	3.25
Zirconium	0.01	to	2.50

1.2 The test methods in this standard are contained in the sections indicated below:

	Sections

Aluminum, Total, by the 8-Quinolinol Gravimetric Method (0.20 % to 7.00 %)	100
Carbon, Total, by the Combustion-Thermal Conductivity Method	Discontinued
Carbon, Total, by the Combustion Gravimetric Method (0.05 % to 1.10 %)	Discontinued
Chromium by the Atomic Absorption Method (0.006 % to 1.00 %)	165
Chromium by the Peroxydisulfate Oxidation—Titration Method (0.10 % to 33.00 %)	175
Chromium by the Peroxydisulfate-Oxidation Titrimetric Method	Discontinued
Cobalt by the Ion-Exchange-Potentiometric Titration Method (2 % to 75 %)	53
Cobalt by the Nitroso-R-Salt Spectrophotometric Method (0.10 % to 5.0 %)	61
Copper by Neocuproine Spectrophotometric Method (0.01 % to 10.00 %)	90
Copper by the Sulfide Precipitation-Electrodeposition Gravimetric Method (0.01 % to 10.00 %)	71
Iron by the Silver ReductionTitrimetric Method (1.0 % to 50.0 %)	192
Manganese by the Periodate Spectrophotometric Method (0.05 % to 2.00 %)	9
Molybdenum by the Ion Exchange—8-Hydroxyquinoline Gravi- metric Method (1.5 % to 30 %)	184
Molybdenum by the Spectrophotometric Method (0.01 % to 1.50 %)	153
Nickel by the Dimethylglyoxime Gravimetric Method (0.1 % to 84.0 %)	135
Phosphorus by the Molybdenum Blue Spectrophotometric Method (0.002 % to 0.08 %)	19
Silicon by the Gravimetric Method (0.05 % to 5.00 %)	46
Sulfur by the Gravimetric Method	Discontinued
Sulfur by the Combustion-Iodate Titration Method (0.005 % to 0.1 %)	Discontinued
Sulfur by the Chromatographic Gravimetric Method
Tin by the Solvent Extraction–Atomic Absorption Method (0.002 % to 0.10 %)	143

1.3 Methods for the determination of carbon and sulfur not included in this standard can be found in Test Methods E1019.

1.4 Some of the composition ranges given in 1.1 are too broad to be covered by a single method and therefore this standard contains multiple methods for some elements. The user must select the proper method by matching the information given in the Scope and Interference sections of each method with the composition of the alloy to be analyzed.

1.5 The values stated in SI units are to be regarded as standard.

1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific hazards statements are given in Section 6 and in special “Warning” paragraphs throughout these test methods.